Cu₃ N弹性和热力学性质的第一性原理研究     

李世娜  刘永 《海洋学报》2010,32(10):6882-6888

利用基于密度泛函理论的第一性原理全势线性缀加平面波方法,研究了立方反ReO₃结构Cu₃N在零温(0 K)零压下的平衡晶格常数、体弹模量及其对压强的一阶导数,计算结果与其他实验及理论结果基本相符. 同时得出Cu₃N的弹性常数,Poisson比等,并分析出Cu₃N在零温零压下是稳定的. 通过准谐Debye模型计算Cu₃N的热力学性质,得到了Cu₃N的晶格常数、等压比热容、等容比热  相似文献   

澜沧江中下游斜坡稳定性评价预测的理论与方法探讨     

周钜乾  唐川 《云南地理环境研究》1995,7(1):29-38

本文以澜沧江下游流域边坡稳定性评价为实例，对模糊评判模型的应用问题和处理技术进行了论述。认为该模型简便实用、效果稳健、适应性强，是边坡稳定性评价工作中适宜推广的一个实用模型。此外，文中还提出了用于模糊评判模型的信息检验法，讨论了这一方法在遴选有效评价因子和优化模型效能中的作用。  相似文献   

国产WSP—2半米平面光栅测定超痕量金方法介绍     

丘文照 《铀矿地质》1990,6(1):59-62

本文叙述了国产半米平面光栅光程短、光强好、谱线锐度佳的特点,通过最佳条件选择,改进分析方法,使其测金灵敏度为3×10~(-9)g,取样10g可测定含金量范围为0.3—1000ppb,取得了很好的效果。  相似文献   

磁层顶等离子体中的混沌现象     

王乃权 《地球物理学报》1991,34(4):523-526

本文研究了磁层顶等离子体的一个基本模型,得到了一新的非线性常微分方程组.数值分析表明,在一定的磁Reynolds数范围内,系统呈现混沌行为,相轨道趋向于奇异吸引子.  相似文献   

亮点周围的衍射模式          下载免费PDF全文

刘伟霞  栾文贵 《地球物理学报》1994,37(3):370-381

将衍射问题研究中的回波解析奇性归结为探讨含参量的振荡积分的渐近性态问题，并利用广义函数的算子理论，以十分简捷的方式给出了上述振荡积分的稳定位相公式，以及结合Ｔｈｏｍ理论逐一地算出非退化奇点、岐点和脐点周围的衍射模式．  相似文献   

有限元素法全倾角波动方程偏移   总被引：4，自引：1，他引：4       下载免费PDF全文

王尚旭  牟永光 《地球物理学报》1989,(3)

本文试图从两个方面提高波动方程偏移的效果:1.使用全方向波动方程进行偏移,使之适用于任意倾角界面的反射;2.使用有限元素法提高微分方程数值解法的精度。  相似文献   

Oxygen deficient perovskites in the system CaSiO3–CaAlO2.5 and implications for the Earth’s interior     

U. W. Bläß  F. Langenhorst  D. J. Frost  F. Seifert 《Physics and Chemistry of Minerals》2007,34(6):363-376

Oxygen deficient perovskites of the system CaSiO₃–CaAlO_2.5 have been synthesised at high-pressure and -temperature conditions relevant to the Earth’s transition zone in order to investigate their stabilities in the Earth’s mantle and determine structural properties associated with vacancy incorporation. Two polysomes of thermodynamically stable defect perovskites with Ca(Al_0.4Si_0.6)O_2.8 and Ca(Al_0.5Si_0.5)O_2.75 stoichiometry have been identified. The ordering of oxygen defects into pseudo-cubic (111) layers results in well-ordered ten- or eightfold superstructures, respectively. At all other compositions examined, a metastable formation of perovskites has been observed instead, which are assumed to grow initially disordered. These are now characterised by tiny domains, formed due to subsequent ordering of vacancies along various pseudo-cubic {111} layers. Both ordered defect perovskites show a large P–T stability field ranging from about 9–18 GPa and 4–12 GPa, respectively. Microstructural TEM analyses revealed the presence of growth and ferroelastic twins, which indicate a phase transition from rhombohedral to monoclinic symmetry during quenching. Electron energy loss spectroscopy of Si and Al K edges point at the presence of tetrahedral, octahedral and maybe some pentacoordinated silicon, whereas aluminium is predominantly octahedrally coordinated with minor fractions in lower coordination. Observed properties are interpreted in terms of a new structural model, explaining the observed phase transition and formation of different twin laws as well as giving reasons for the development of such large superstructures. With respect to phase relations of the transition zone, the potential occurrence of such defect perovskites in the Earth’s interior is discussed.  相似文献   

简单热带海气耦合模型中的缓慢扰动Ⅰ:对称和反对称于赤道的运动     

林一骅  傅云飞 《气象学报》2001,59(1):1-9

文中讨论了在局地热平衡情况下简单模式中的热带海气耦合扰动，指出参数K  相似文献   

简单热带海气耦合模型中的缓慢扰动I:对称和反对称于赤道的运动     

林一骅  傅云飞 《气象学报》2001,(1)

文中讨论了在局地热平衡情况下简单模式中的热带海气耦合扰动 ,指出参数 KH,KS和α决定着耦合扰动性质 ,并研究了使用抛物线柱函数展开时所截项数多寡对耦合扰动性质的影响以及对称和反对称于赤道的耦合扰动特征  相似文献   

Rotation and dilation deformation mechanisms for auxetic behaviour in the α-cristobalite tetrahedral framework structure     

A. Alderson  K. E. Evans 《Physics and Chemistry of Minerals》2001,28(10):711-718

 Analytical expressions are derived for the Poisson's ratios associated with a three-dimensional network of regular, corner-sharing tetrahedra in which: (1) the tetrahedra are assumed to be rigid and free to rotate relative to each other; (2) the tetrahedra are assumed to maintain shape and orientation but are free to change size (dilate); (3) tetrahedral rotation and dilation are assumed to act concurrently. The structure has a primitive unit cell containing four tetrahedra and is analogous to the molecular structure of α-cristobalite. Strain-dependent variations in Poisson's ratio are also predicted by the models. For deformation due to tetrahedral rotation the network is found to exhibit negative Poisson's ratios in each of the three principal directions, with the magnitude of the Poisson's ratio being dependent on the angle of rotation of the tetrahedra. The behaviour of the Poisson's ratio is isotropic in the transverse plane, but anisotropic elsewhere. In the dilation model negative Poisson's ratios equal to −1 are observed for uniaxial loading in any of the principal directions, with the value being constant irrespective of tetrahedral size. The model for concurrent tetrahedral rotation and dilation allows positive as well as negative Poisson's ratios, with the values determined by the framework geometry and relative strengths of the two mechanisms. The concurrent model also offers a design route to materials and structures having ultrahigh Young's moduli. Received: 15 February 2000 / Accepted: 1 October 2000  相似文献